Orange-To-Black Halloween Clock Reaction

The Old Nassau or Halloween reaction is a clock reaction in which the color of a chemical solution changes from orange to black. Heres how you can do this reaction as a chemistry demonstration and a look at the chemical reactions that are involved. Halloween Chemical Reaction Materials WaterSoluble starchSodium metabisulphite (Na2S2O5)Mercury(II) chloridePotassium iodate (KIO3) Prepare the Solutions Solution A: Mix 4 g soluble starch in a couple milliliters of water. Stir the starch paste into 500 ml boiling water. Allow the mixture to cool to room temperature. Add 13.7 g of sodium metabisulphite. Add water to make 1 liter of solution.Solution B: Dissolve 3 g mercury(II) chloride in water. Add water to make 1 liter of solution.Solution C: Dissolve 15 g potassium iodate in water. Add water to make 1 liter of solution. Perform the Halloween Chemistry Demonstration Mix 50 ml solution A with 50 ml of solution B.Pour this mixture into 50 ml of solution C. The color of the mixture will change to an opaque orange color after a few seconds as the mercury iodide precipitates. After another few seconds, the mixture will turn blue-black as the starch-iodine complex forms. If you dilute the solutions by a factor of two then it takes longer for the color changes to occur. If you use a smaller volume of solution B the reaction will proceed more rapidly. Chemical Reactions Sodium metabisulfite and water react to form sodium hydrogen sulfite:Na2S2O5 H2O → 2 NaHSO3 Iodate(V) ions are reduced to iodide ions by the hydrogen sulfite ions:IO3- 3 HSO3- → I- 3 SO42- 3 H When the concentration of iodide ions becomes sufficient for the solubility product of the HgI2 to exceed 4.5 x 10-29 mol3 dm-9, then orange mercury(II) iodide precipitates until the Hg2 ions are consumed (assuming an excess of I- ions):Hg2 2 I- → HgI2 (orange or yellow)If I- and IO3- ions remain, then an iodide-iodate reaction takes place:IO3- 5 I- 6 H → 3 I2 3 H2OThe resulting statch-iodine complex is black to blue-black:I2 starch → a blue/black complex

What is Culture Essay examples - 1828 Words

The first definition of ‘culture’ by Oxford’s Dictionary is ‘art, literature, music and other intellectual expressions of a particular society or time’ (â€Å"Culture,† Oxford’s Advanced Learner’s Dictionary of Current English). Anthropologist of culture, Raymond Williams argued that the term ‘culture’ was first used in reference to the cultivation of crops which was later associated in relation to the cultivation of the human mind, hence the expression ‘cultured/cultivated person’. The noun of process thenceforth grew into a noun of configuration in the later 18th century where culture meant ‘the generalisation of the ‘spirit’ which informed the ‘whole way of life’ of a distinct people’ (Williams, 1981) implying a common ‘way of life’ shared†¦show more content†¦Marx, as cited in Chris Barker’s Cultural Studies – Theory and Practi ce, argued that human beings main concern is to produce their means of survival, i.e. food and clothes, through labour consequently creating themselves. He further argued that in the capitalist society, culture equals power as the bourgeoisies – those own the economic means and relations of production, controls the cultural production, the distribution mechanisms of cultural products and the cultural structure of a society – i.e. art, culture and politics. Economic determinism although is not autonomous, is essential to the understanding of culture where the structure and meaning of a specific cultural product is determined by the profit-driven motive and class relations where it examines the cultural trend in terms of their ‘own rules, logics, development and affectivity’ (Barker, 2009: 56). Marx predicted that with the arrival of capitalism, consequently comes the fall of it as the conflict of class will drive the proletariats, the labourers, to overthro w capitalism through organizations of defence, trade unions and political parties thus replacing it with a class-less society, and common ownership and unbiased allotment of products. Marx, together with Frederick Engels, argued that the ideas instilled in the proletariat’s mind are only the ideas of the ruling class driven by materialistic conditions. TheseShow MoreRelated What is Culture?1459 Words   |  6 PagesQuestion One What is culture? Culture can be interpreted in multiple ways and have many different meanings to different individuals. Consequently, it is because of those facts that a definition is so hard to create. To some, culture results from consumed meanings by a social group (Lewis, 2008). Others view culture as something based on economics and servitude (Marx, as cited by Lewis, 2008). Hebdige ambiguous concept As I attempt to tease out a personal definition of culture based on my ownRead MoreWhat is Culture?1622 Words   |  7 PagesWebster’s dictionary defines culture as â€Å"the beliefs, customs, arts, etc., of a particular society, group, place, or time†. (Culture) This paper will attempt to inform the reader of those influences that were instrumental in molding what is the modern culture of Italy. The geography, history, language, art, food, and religion of the Italian region all combine to form one of the richest cultures on planet earth. This culture has also been a key influencer of western culture as a whole. By better understandingRead MoreWhat Makes A Culture Or Culture?2443 Words   |  10 Pages Chapter Four 4.1 Helpful for My Career: Choosing a culture or cultures to learn about would help me to understand the way of doing business in other countries. 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Newsweek Free Essays

string(43) " of a hotel on Memphis earlier that month\." Sometimes, the more things change, the more they stay the same. This is true, at least to some degree, in the study of these articles. They deal with three issues: Politics, Race and Sports and Entertainment. We will write a custom essay sample on Newsweek or any similar topic only for you Order Now People are still interested in politics, though Congress, with a 14% approval rating, more people are annoyed than interested. However, the importance has not diminished. Also, race is still an issue. The 1964 and 1968 articles on race deal with the upcoming elections and how African Americans are expected to vote. Also, the assassination of Martin Luther King Jr and the political undertones that they will carry is also heavy on the minds of the country. In sports, the Olympics and the Boston Marathon command small attention. What is seen as one of the biggest differences from the 1964 and 1968 Newsweek articles in comparison to the 2007 Newsweek, that that a larger percentage of the magazine in 2007, deals with Sports, Entertainment and popular culture. Even for such a respected magazine as Newsweek, the editors cannot escape the exponential increase in popular culture at the expense of real news, which the country seems to hunger for on an hourly basis. In the November 2, 1964 issue of Newsweek, the issue revolves around the Presidential election that is about to come later that week. The political tension is not as heavy as in past elections since everyone believes that the result will be a landslide. President Johnson is expected to beat Arizona Senator Barry Goldwater by a very large margin. Goldwater, a Republican, is hoping to court the morality vote and to point to Johnson as being soft on communism. President Johnson , in a speech in Belleville, IL talked about the dangers of nuclear war and that, like his predecessor before him, President Kennedy, believes that the next war will be one in which there are no survivors. â€Å"We would not gain total victory in the next war, but total destruction and the survivors would be the judges of the dead.† (Meyers, 1964 pg. 23) He is referencing the dangers of a nuclear war. The war in Vietnam is gaining strength and troop levels are rising. The article points to the promise that if elected, President Johnson would help to â€Å"avoid a war in South East Asia.† In reality, the exact opposite will come to fruition. Due to the fact that the election is near, the next issue of Newsweek, deals with the demographics of the voters and how they voted. Most findings will report that Johnson won most of the demographics since his margin of victory was 486 to 47 in electoral votes. It will remain as one of the most lopsided victories in American political history. What is interesting in this article entitled The Mood of an Avalanche, is the fact that African Americans, individuals who voted for the straight Republican ticket since Andrew Johnson, now voted overwhelmingly for President Johnson. It is reported that 96% of the African American voters voted for President Johnson. (Mulligan, 1964 pg. 24) This is due in part to the fact that Senator Goldwater courted the Segregationist vote in the South to such a degree that African Americans turned away from him in droves. In one Mississippi small town in which there counted only 257 voters, the article reports that all 257 voted for Johnson. This article is important in dealing with race and how it affects the voting demographics since African Americans will vote for the straight democratic ticket from now on. In Sports and Entertainment, the 1964 Olympics is proceeding. In a Newsweek article entitled The Gold Rush, the fact that the Americans are leading the medal total, is a story. However, one of the most famous stories revolved around the Native American runner Billy Mills. Movies would be made about this person. Born into poverty and enduring racism at every turn, Billy Mills would become a champion runner. His main event was the 10,000 meter run. During this event in the Olympics, Billy Mills was pushed by another runner onto the outside of the track. Usually, this serves as a great impediment to the runner. However, Mills, against the prevailing knowledge of track and field, once pushed, continues to run in the middle of the track on the middle lane. This forces Mills to run longer distances than his opponent. However, not only does Mills win, but he creates an Olympic record in the event in the process. It is the inspirational story for the18th Olympics. Fast forward to 1968 and the political scene still deals with President Johnson. However, things have not been going well for him. 1968 would be the year that saw more than 500,000 American troops in Vietnam. Clearly, President Johnson would not be the President to keep America out of the war. In a Newsweek article dated April 22, 1968, the fact that Robert Kennedy is running for President as well and has forced President Johnson to say that he will not run for the presidency that year. His tenure will end on January 20, 1969. The article talks about the influence that a number of different factors and how they will play into the election. The first is Robert Kennedy. The second is the Republican Candidate, Richard Nixon. â€Å"Nixon lost the 1960 election because the 1960 televised Presidential debate, left the country feeling as though Mr. Nixon was not as likable and trusting as John F. Kennedy.† (1968 pg. 32) The question now is, eight years later, how will television affect the election and how will Mr. Nixon respond. There is also a report in the article entitled Politics ‘68, what demographics will vote for which candidate. The demographics are divided into race, gender, religion, occupation and regions of the country. By the end of April, 1968, the country is still reeling from the assassination of Martin Luther King Jr. He was killed on the balcony of a hotel on Memphis earlier that month. You read "Newsweek" in category "Essay examples" Riots in most of the country’s largest cities occurred and many people died. â€Å"The arithmetic of the week’s pillage was more than enough. Civil disorders raging from riots to random shop windows breaking, occurred in more than 130 cities and caused an estimated $5 million worth of damage. More than 20,000 arrests and endless injuries have been the result.† (Jules, 1968 pg. 47) 1968 was one of the hardest years for the American public to endure. The assassination of Martin Luther King was one of those reasons and added to the madness of the situation. Many wondered in the article where the Civil Rights movement would turn to next. What leader would take the reigns? To many, people are still asking the same question. In Sports, the 72nd Boston Marathon was reported as being under way in the April 29, 1968 issue of Newsweek. Out of a total of 890 runners, the winner boasted a winning time of 2 hours twenty two minutes and seventeen seconds. This was not a great time. However, it was run by an American, the first American to win the Boston Marathon since 1957. (Jones, 1968 pg. 38) His name was Ambrose Burfoot, aged 21. Burfoot beat all others by a sizable margin but not one which would endure posterity. However, the fact that Burfoot was an American, then as well as now, is an important note as it has been the running feats of foreigners which has dominated the winner’s circle at the Boston marathon. I In the January 8, 2007 edition of Newsweek, the main story is the death of Saddam Hussein. The once feared leader of Iraq who was found hiding in a spider hole in December of 2003, was finally put to death. The article entitled Death of a Tyrant, headlines the life and legend of the man and the reign of terror that he placed upon his people for so many decades. The article also speaks to the trouble which occurred from a secret video tape being smuggled out of the area where Saddam was killed. This was in direct opposition to the orders of both the American and Iraqi forces. Such images was believed to help incite riots among the enemy and was by a public relations point of view, counterproductive. Also, in politics, the death of President Ford was the news for the week as well. The article details the life of President Ford and how he was able to heal the country after the scandal of Watergate. The article finally gives credit to Ford by saying that pardoning President Nixon was the right thing to do as it helped the country to heal. In Race, the production of O.J. Simpson’s book If I Did It, produced such an outrage that production was stopped. A January 22, 2007 Newsweek article details this. This is a racial issue because the beliefs regarding his innocence or guilt for the 1994 death of his wife, Nicole Brown Simpson and her friend, Ron Goldman, was so split on racial lines that it still incites controversy. More than 80% of white Americans believe that OJ is guilty and over 80% of African Americans believe that he is not. (Brunell, 2007 pg. 48) That is why anything that deals with OJ Simpson and the murders, is dealt with on racial lines. The fact that he wrote a book that served as a sort of quasi confession, enraged many Americans and forced his supporters to wonder if he really was guilty of the murders for which he was charged. In Sports and Entertainment, a sad story was detailed in the January 15, 2007 issue of Newsweek. In a time of divisive issues which help to split the country up into racial and political lines, Steve Irwin the Crocodile Hunter was an individual who everyone seemed to have a positive opinion about. His popular show detailed frequent run ins with some of the world’s most dangerous animals. Over the past few years, he had become highly popular and when speaking of the name of Steve Irwin, most people had a positive opinion of the man. This ended when a sting ray pierces through his heart and killed him. This served as important news all over the country as well as for the rest of the world. What is interesting to note, through a study of these three separate dates, is that many things still stay the same. There are more colorized pictures in the 2007 Newsweek and there are more articles designed towards Sports and entertainment in the 2007 Newsweek, but race and politics are still important. The 1964 and 1968 editions of Newsweek death with both. The elections in 1964 and 1968 served as some of the more important elections in the country’s history. How would the Vietnam War continue? Would the Civil Rights movement continue with the help of the White House and members of Congress? And if not, how would African Americans vote and who did they believe gave the best chance at equality? These issues are much the same in 2007. The Vietnam War has been replaced with the war in Iraq, although not nearly to the same degree as the Vietnam War. African Americans still vote the straight Democratic ticket. In 2000 and 2004, African Americans voted for the Democratic presidential candidate at a rate of more than 9 to 1. The same can be seen in the attempted release of the OJ Simpson book. If I did It. The news of this released such anger from most of the public and incited an argument which brought back, although to a much less degree, the racial tension that was caused from the famous trial and acquittal. WORKS CITED Decklan, M Death of a Tyrant   Newsweek. January 8, 2007 Jones, L. The Gold Rush. Newsweek October 26, 1964 pg. 13 Jules, J. The Death of Martin Luther King Newsweek. April 22, 1968 pg. 45 Kilmer, F Final Hunt for Steve Irwin. Newsweek January 15, 2007 Meyers. J Down to the Wire. Newsweek Magazine November 2, 1964 pg. 23-27 Mulligan, L. The Making of an Avalanche November 9, 1964 pg. 28-21 Nieves, D. OJ’s Troubles Continue Newsweek January 22, 2007 Stevens, K. American Wins Boston Marathon. April 29, 1968 pg. 32 RFK vs. LBJ? Newsweek April 29, 1968 pg. 12 How to cite Newsweek, Essay examples

Concealed Carry free essay sample

The shooter also was killed by his own hand. With the death toll at 26, the Newtown shooting is the second deadliest school shooting in U. S. istory, behind only the 2007 shooting at Virginia Tech that left 32 people dead, and you know how this was all possible, because the faculty was not allowed to be armed on school grounds thus there was no one able to stop this evil doer before the body count escalated. So if you get nothing else from this paper I hope you can understand that we should at least arm our teachers. Because of the increase in criminal activity more law-abiding citizens are going to want some means of protecting themselves, Thus more people want a concealed weapon. As David Kopel stated in his article Guns in the Right Hands Make Society Safer In responsible hands, guns are no danger at all, since the gun will only shoot in the direction in which it is pointed. We will write a custom essay sample on Concealed Carry or any similar topic specifically for you Do Not WasteYour Time HIRE WRITER Only 13.90 / page (Roleff 13) About any American may possess a handgun for home protection except of course felons and the mentally ill. The question of concealed carry can be reduced to one of the most perplexing conundrums in politics which comes first, the safety and well-being of the individual, or everyone? Most people would immediately and instinctively say everyone. But what if that certain individual is you? Does society have the right to prevent you from pursuing, and protecting your own self interest? Gregory Curtis The right to defend yourself and your loved ones from criminals is fundamental, That is why it is vital for the people to be able to defend themselves and their loved ones should the need arise. Christopher W Cox and Rep. Clifford B. Steams. Now Despite the danger there is a reason why people are wanting to pack some heat quite a few people will save their lives by pulling out their guns to stop the thug coming at them. Preventing people from protecting themselves with handguns does not end violence, But just makes them more vulnerable to being attacked. John r. Lott Jr. Gun ownership for home protection is considerably more beneficial to the entire community and many other anti-burglary measures. David Kopel The use of concealed handguns by permitted citizens may cause a positive externality [enjoying a benefit for which one d id not pay] for others. since they are concealed, criminals will not be able to tell who is armed before they attack raising the risks of the crime. John R Lott Junior. People who support law abiding citizens concealed carry, polls showing that Americans defend themselves between 764,00 and 3. 6 million times each year in some cases simply being the Citizen brandishing the gun to Prevent attack. John R Lott Junior Concealed handguns also seem to be the great equalizer between the sexes. Murder rates decline it either more women or men carry, its more noticeable for women than men by about 3 to 4 times more then an additional man carrying John R Lott Junior In New Jersey state constitution says in its preamble at the right of self-defense Is in alienable Michael J Hartmann New Jersey has had the toughest gun laws almost any state. Has that stopped criminal from Being armed? Chris A. Kusmanick. Every mass shooting in the last 25 years have been in places where firearms are banned. nobody wants to be Rambo or go out there to save the world, but at Virginia Tech people spent nine minutes under desks hoping and praying that they didnt run out of time. We dont want that be in that situation. Daniel Crocker. People who carry illegally are what you call free riders the term comes from many examples such as: late at night with no one around someone goes over the subway turnstile so he can ride for free. Technically, he broke the law but who did he hurt by doing this, No one. Now if everyone did it the subway system would go bankrupt. Both the gun carrier and the turnstile jumper have decided to accept the risk of getting caught. As the saying goes better to be judged by 12 than be carried by six. from societys point of view, the free rider is a menace. But from the free riders point of view, what has he done that is so terrible? He did something to benefit himself, and no one was hurt and nothing change. Gregory Curtis Changing the laws on concealed guns would be a step in the right direction. Having a gun handy (and being properly trained to use it) will not prevent all crime but Id rather have a fighting chance no chance at all. So far, similar laws and other states have been a solid success story, and have not resulted in the blood drenched streets that were so melodramatically predicted by the media. Michael J Hartmann Now about the innocent neighbors frequently being shot, the police accidentally killed 300 innocent citizens in 1993 while only 30 were killed by private citizens who thought them intruders. I personally believe people can control themselves in the heat of the moment and not just throw the gun around for instance. There was only one reported case in the entire nation, of a legal handgun shooting following an aut o accident, and it was ruled to be self-defense by motorist was being beaten. Lott and Mustard We have the technology to personalize our guns to where only the authorized person may use the weapon. This can help reduce the rates of homicide, suicide, and accidental deaths. Some technologies developed to personalize guns are magnetic encoding, touch memory, and radio frequency. Once personalized guns replace present day guns that are operable by anyone, the unauthorized use of guns by children and adolescents will decrease. John R Lott Junior Suicide is among one of the leading causes of death for young people like in 1995 more than 2200 people between 10 and 19 committed suicide in the US and 65% of them use a gun. Now if you personalize the guns to the adult owner it would be very less likely for this to happen Some people will argue that the best way of protecting our children would be to gun proof them but why not just childproof guns. It is however very important on the adults part to keep guns away from children and children have to try and keep away from guns however about 40% of American homes have firearms not all parents can be relied upon to store their guns safely and properly. People have documented unsafe storage practices, even from people properly trained in gun safety are among those documented surveys. Every state but Illinois makes some allowance for concealed weapons the rules may be different and each state decides whether to honor another states permits. Unknown author Vermont has long had the least restrictive firearms carry laws, allowing citizens to carry guns either openly or concealed without any permit. Vermont also has maintained once the lowest violent crime rates i n the country. . David Kopel. The states permitting concealed carry are saving lives I studied by John R Lott Junior and David B mustard using 15 years of data from every county in the nation found that allowing citizens to carry handguns deters violent crimes. Now if every state did it in 1992 citizens would have been spared about 1520 murders, 4177 rapes, 60,363 ddaggravated assaults, and 11,898 robberies. Counties with populations over 200,000, concealed handgun laws produced an average drop and murder rate by 13% and the half of counties with the highest murder rate experience over 10% drop in murders and the counties with the highest rate account so I fall of over 7%. John R Lott Junior. But of course with the lowering of violent crimes the more stealthy crimes like larceny or auto theft rise by about two or 3% now personally I could accept this as a fair trade-off. Point 2 Okay lets go ahead and start talking about the criminal aspect of the concealed carry laws. In an article written by Michael J. Bulzomi he stated that â€Å"In 1968, Congress enacted the federal gun-control act. 19 prohibiting felons from possessing a firearm. † Well apparently the scum of this earth didn’t get the memo when it came to this act. If people want guns, especially criminals there is nothing you can do to stop them, the choice is whether or not to get one legally from you or illegally from say other criminals or the black market. Like Sasha Abramsky said â€Å"If you stopped all gun sales tomorrow you would still have a population so outfitted with weaponry it would be better than most foreign militaries. You may be able to lower the amount of people shot by legal guns but you would never be able to fully rein in a black market totally stacked with guns. † Many illegally sold guns to criminals were stolen from homes and the research done on the guns used for crime show that many are no more than a couple years old. With so many guns stolen, then used, I propose that since such technology exists making it possible to personalize a gun we should, to ake it inoperable by anyone but the permitted adult owner. We should require the technology to be put in to the weapon while it is still in the factory. Then like for police officers, they wont have to worry about being shot with their own guns If the criminals they are trying to arrest takes it and tries to use it on them. I Also agree with John R. Lott Jr. â€Å"requiring all guns to be personalize could therefore limit the availability of useful guns to criminals and the illegal gun market. † A good amount of gun related deaths are caused by stolen guns about 500,000 guns are stolen a year and a survey of criminals both adult and juvenile indicate that those guns stolen make up are a significant portion of the weapons used for crime about one third of the guns used by felons are obtained directly through theft. Okay from what I have said thus far it is understandable that the U. S. A has a very high rates of violent crime more so than most other industrial democracies. The crime rate is high for the crimes that usually involve a gun, crimes with less use of guns such as rape are also high by about 7 percent. John R. Lott Jr. about covers it with â€Å"Now by virtue of the fact that handguns are concealed, criminals are unable to tell whether a potential victim is able to defend herself or himself until they attack, thats making it look less attractive for criminals to commit crimes where it is possible they might come into direct contact with the victim. † I believe that most felons are cowards at heart, in a survey of 73% of convicts, convicts agreed â€Å"one reason burglars avoided houses when people are home is that they feared being shot† and in â€Å"another study 90% of burglars wouldnt even attempt a house they thought might be occupied. so says David Kopel. â€Å"The fear of potentially armed victims cause American burglars to spend more time than their foreign counterparts casing house to ensure no ones home. Felons frequently comment that they avoid late night burglaries because thats the way you get shot. † John R. Lott Jr. â€Å"The potential defensive nature of guns indicated by different rates of so-called â€Å"hot† burglaries were victims/residents are at home when the criminal decides to strike almost half the burglaries in Canada and Britain which have strict gun control laws) are hot by contrast the United States has a hot rate of only 13%. surveys of convicted felons in America reveal that they are more worried about an armed victim then they are running into the police† John R. Lott Jr. The national Institute of Justice did a study estimating the cost of different crimes their findings show that allowing concealed carry would have given you again of about $574 billion in 1992 the reduction of violent crime gives you a gain of $6. 2 billion (4. 8 billion for murder, 1. 4 billion from aggravated assault, $374 million from rape, and $98 million from robbery. ) While the increase in property crimes gives you a loss of $417 million (343 million from auto theft, 73 million for larceny, and 1. 5 million from burglary. ) So do to our gun laws and the allowance of our people to have guns. American homes are safer then that that of England’s or Canada’s especially from hot burglaries â€Å"only about 13% of residential burglaries in the U. S. are attempted against occupied homes. â€Å"In Canada the study found that 48% of burglaries were against occupied homes and 21% involved a confrontation with the victim. † David Kopel â€Å"In 1982 kennesaw, Georgia passed an ordinance requiring every home to have a gun ,(exceptions were made of course for some people) seven months before there had been 45 residential burglaries, seven-month after theres only five an 89% decline over the next five years, the residential burglary rate in kennesaw was 85% below the rate before the enactment of the ordinance. The US Supreme Court and lower courts have held that the police are not obligated to protect individuals from crime, citizens are ultimately responsible for their own defense. Which I can see really theres no way you can put the amount of officers needed on the street to be personal bodyguards to everyone man woman or child. Orlando 1967 police responded to a rate epidemic by initiating a highly publicized program training women firearms use while rate increase the nation over the next year the rate rate fell 88% in Orlando and burglary dropped 22%. David Kopel Virginia Tech was designated a gun free zone by the ministration so that people would feel safe on campus Sadly they werent safe now killers on other campuses were stopped by faculty or bystanders with concealed weapons this didnt happen at Virginia Tech. This putting a sign in the window or banning weapons in a store saying you cant carry a weapon pass these doors, if a criminal sees that hes Not going to be like oh theres a sign I cant go in there I cant rob this place. It doesnt matter to the criminal if there is a ban on guns or its a gun free zone, so youre basically taking away the only means of protection if some maniac comes in their and shoot up the place or rob or kill or Massacre, The general public. While most criminals avoid crimes like robbery due to the carry laws sadly they dont just give up doing crime they just do jobs that the risk of meeting someone armed is much lower like property offenses such as larceny and auto theft.